Batteries

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Revision as of 00:13, 18 April 2016 by Leo 037 (Talk | contribs) (NCA et LTO)

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Objectif

  • obtenir des batteries au prix le plus bas possible, impliquant probablement un assemblage maison de cellules
  • acquérir des connaissances dans le domaine des batteries, faire les choses selon les normes en vigueur, ne pas compromettre la sécurité

Applications

Batteries Lithium-ion

https://en.wikipedia.org/wiki/Comparison_of_battery_types

https://en.wikipedia.org/wiki/Lithium-ion_battery

Handheld electronics mostly use LIBs based on lithium cobalt oxide (LiCoO2), which offers high energy density, but presents safety risks, especially when damaged.

Lithium iron phosphate (LiFePO4), Lithium ion manganese oxide battery (LMnO or LMO) and lithium nickel manganese cobalt oxide (LiNiMnCoO2 or NMC) offer lower energy density, but longer lives and inherent safety. Such batteries are widely used for electric tools, medical equipment and other roles. NMC in particular is a leading contender for automotive applications.

Lithium nickel cobalt aluminum oxide (LiNiCoAlO2 or NCA) and lithium titanate (Li4Ti5O12 or LTO) are specialty designs aimed at particular niche roles.

The new lithium sulphur batteries promise the highest performance to weight ratio.

http://batteryuniversity.com/learn/article/types_of_lithium_ion

Formes

Li-ion cells (as distinct from entire batteries) are available in various shapes, which can generally be divided into four groups:

  1. Small cylindrical (solid body without terminals, such as those used in laptop batteries)
  2. Large cylindrical (solid body with large threaded terminals)
  3. Pouch (soft, flat body, such as those used in cell phones)
  4. Prismatic (semi-hard plastic case with large threaded terminals, such as vehicles' traction packs)

https://en.wikipedia.org/wiki/Lithium_polymer_battery

A lithium polymer battery, or more correctly lithium-ion polymer battery (abbreviated variously as LiPo, LIP, Li-poly and others), is a rechargeable battery of lithium-ion technology in a pouch format. Unlike cylindrical and prismatic cells, LiPos come in a soft package or pouch, which makes them lighter but also less rigid.

[...] "polymer" refers more to a "polymer casing" (that is, the soft, external container) rather than a "polymer electrolyte". While the design is usually flat, and lightweight, it is not truly a polymer cell, since the electrolyte is still in liquid form, although it may be "plasticized" or "gelled" through a polymer additive.

LiFePO4

http://batteryuniversity.com/learn/article/types_of_lithium_ion

LMnO / LMO

http://batteryuniversity.com/learn/article/types_of_lithium_ion

high thermal stability and enhanced safety, but the cycle and calendar life are limited.

Low internal cell resistance enables fast charging and high-current discharging. In an 18650 package, Li-manganese can be discharged at currents of 20–30A with moderate heat buildup. It is also possible to apply one-second load pulses of up to 50A. A continuous high load at this current would cause heat buildup and the cell temperature cannot exceed 80°C. Li-manganese is used for power tools, medical instruments, as well as hybrid and electric vehicles.

Design flexibility allows engineers to maximize the battery for either optimal longevity (life span), maximum load current (specific power) or high capacity (specific energy). For example, the long-life version in the 18650 cell has a moderate capacity of only 1,100mAh; the high-capacity version is 1,500mAh.

Most Li-manganese batteries blend with lithium nickel manganese cobalt oxide (NMC) to improve the specific energy and prolong the life span. This combination brings out the best in each system, and the LMO (NMC) is chosen for most electric vehicles, such as the Nissan Leaf, Chevy Volt and BMW i3. The LMO part of the battery, which can be about 30 percent, provides high current boost on acceleration; the NMC part gives the long driving range.

Lithium Manganese Oxide
Voltages 3.70V (3.80V) nominal; typical operating range 3.0–4.2V/cell
Specific energy (capacity) 100–150Wh/kg
Charge (C-rate) 0.7–1C typical, 3C maximum, charges to 4.20V (most cells)
Discharge (C-rate) 1C; 10C possible with some cells, 30C pulse (5s), 2.50V cut-off
Cycle life 300–700 (related to depth of discharge, temperature)
Thermal runaway 250°C typical. High charge promotes thermal runaway
Applications Power tools, medical devices, electric powertrains
Comments High power but less capacity; safer than Li-cobalt; commonly mixed with NMC to improve performance.

LiNiMnCoO2 / NMC

NCA et LTO

http://batteryuniversity.com/learn/article/types_of_lithium_ion

Li4Ti5O12 / LTO

Sulphure de lithium

http://batteryuniversity.com/learn/article/types_of_lithium_ion

Modèles de location

Puisque c'est un modèle commercial qui est pratiqué (en particulier s'agissant de certains véhicules électriques), il vaudrait la peine de le décrire/comprendre afin d'en tenir compte et de ne pas passer à côté de solutions économiquement intéressantes.

Ressources

https://en.wikipedia.org/wiki/Rechargeable_battery